Chemistry of hydrocarbon compounds – Saturated compound synthesis – By isomerization
Patent
1995-12-06
1998-01-06
McAvoy, Ellen M.
Chemistry of hydrocarbon compounds
Saturated compound synthesis
By isomerization
502 53, B01J 2034, C07C 513
Patent
active
057057311
ABSTRACT:
In a process for isomerizing C.sub.4 -C.sub.7 alkanes and/or C.sub.6 -C.sub.7 cycloalkanes which is carried out in the presence of hydrogen gas, a chloride additive (e.g., CCl.sub.4 or C.sub.2 Cl.sub.4) and a supported platinum and chlorine-containing catalyst (e.g., Pt/Cl/Al.sub.2 O.sub.3), the catalyst is intermittently reactivated in two steps: first, the hydrogen to feed hydrocarbon ratio is raised (while the chloride level in the feed is either not changed or lowered), and thereafter the chloride level in the feed is increased. Preferably, the fresh catalyst is also preactivated by contacting it with the hydrocarbon feed wherein the hydrogen to feed hydrocarbon ratio is higher and/or the temperature is lower than what is employed in the subsequent isomerization production cycle.
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Cowan John D.
Lin Fan-Nan
Pierce Johnnie R.
Brandes K. K.
McAvoy Ellen M.
Phillips Petroleum Company
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