Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Gas or vapor treating
Patent
1988-05-12
1989-10-03
Konopka, Paul E.
Catalyst, solid sorbent, or support therefor: product or process
Regenerating or rehabilitating catalyst or sorbent
Gas or vapor treating
502 52, 568471, 568479, B01J 2394, B01J 2392, C07C 4527, C07C 4528
Patent
active
048717002
ABSTRACT:
A method of reactivating a catalyst having reduced activity as a result of having been used in producing an unsaturated aldehyde as a main product by catalytic vapor-phase oxidation reaction of propylene, isobutylene or tertiary butanol, said catalyst being a catalytic oxide comprising molybdenum, bismuth and iron with a Mo:Fe atomic ratio of 12:at least 0.1. The method comprises heat-treating the used catalyst at a temperature of 300.degree. to 500.degree. C. in the presence of a flowing oxidizing gas containing at least 5% by volume of molecular oxygen and at least 0.1% by volume of steam.
REFERENCES:
patent: 3882159 (1975-05-01), Callahan et al.
patent: 4052333 (1977-10-01), Lee
patent: 4425255 (1984-01-01), Toyoda
patent: 4604370 (1986-08-01), Sarumaru et al.
patent: 4732884 (1988-03-01), Sarumaru et al.
Deguchi Kozi
Sasaki Masamitsu
Uchida Shin-ichi
Konopka Paul E.
Nippon Shokubai Kagaku Kogyo & Co., Ltd.
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