Chemistry: electrical current producing apparatus – product – and – Having magnetic field feature
Patent
1989-12-29
1991-09-03
Skapars, Anthony
Chemistry: electrical current producing apparatus, product, and
Having magnetic field feature
429 23, H01M 804
Patent
active
050454145
ABSTRACT:
A fuel cell (10) system in which a nitrogen (N.sub.2) gas is used on the anode section (11) and a nitrogen/oxygen (N.sub.2 /O.sub.2) gaseous mix is used on the cathode section (12) to maintain the cathode at an acceptable voltage potential during adverse conditions occurring particularly during off-power conditions, for example, during power plant shutdown, start-up and hot holds. During power plant shutdown, the cathode section is purged with a gaseous mixture of, for example, one-half percent (0.5%) oxygen (O.sub.2) and ninety-nine and a half percent (99.5%) nitrogen (N.sub.2) supplied from an ejector (21) bleeding in air (24/28) into a high pressure stream (27) of nitrogen (N.sub.2) as the primary or majority gas. Thereafter the fuel gas in the fuel processor (31) and the anode section (11) is purged with nitrogen gas to prevent nickel (Ni) carbonyl from forming from the shift catalyst. A switched dummy electrical load (30) is used to bring the cathode potential down rapidly during the start of the purges. The 0.5%/99.5% O.sub.2 /N.sub.2 mixture maintains the cathode potential between 0.3 and 0.7 volts, and this is sufficient to maintain the cathode potential at 0.3 volts for the case of H.sub.2 diffusing to the cathode through a 2 mil thick electrolyte filled matrix and below 0.8 volts for no diffusion at open circuit conditions. The same high pressure gas source (20) is used via a "T" juncture ("T") to purge the anode section and its associated fuel processor (31).
REFERENCES:
patent: 3666562 (1972-05-01), Sprengel
patent: 4657826 (1987-04-01), Tajima
patent: 4657828 (1987-04-01), Tajima
patent: 4859545 (1989-08-01), Scheffler et al.
patent: 4904547 (1990-02-01), Mizumoto et al.
patent: 4963443 (1990-10-01), Kamoshita
Bushnell Calvin L.
Davis Christopher L.
International Fuel Cells Corporation
Skapars Anthony
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