Radiation imagery chemistry: process – composition – or product th – Radiation modifying product or process of making – Screen other than for cathode-ray tube
Reexamination Certificate
2001-03-16
2001-12-04
McPherson, John A. (Department: 1756)
Radiation imagery chemistry: process, composition, or product th
Radiation modifying product or process of making
Screen other than for cathode-ray tube
C430S511000
Reexamination Certificate
active
06326108
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to color filter arrays for use in image capture devices such as digital cameras, scanners and photographic film.
BACKGROUND OF THE INVENTION
The great majority of color photographs today are taken using chromogenic color film, in which color-forming couplers, which may be incorporated in the film or present in the processing solution, form cyan, magenta and yellow dyes by reaction with oxidized developing agent which is formed where silver halide is developed in an imagewise pattern. Such films require a development process which is carefully controlled in respect of time and temperature, which is usually followed by a silver bleaching and a fixing step, and the whole process typically takes several minutes and needs complex equipment.
Color photography by exposing a black-and-white photographic emulsion through a color filter array which is an integral part of the film or plate on which the photographic emulsion is coated, has long been known to offer certain advantages of simplicity or convenience in color photography. Thus the Autochrome process, disclosed by the Lumiere brothers in 1906 (U.S. Pat. No. 822,532) exposed the emulsion through a randomly disposed layer of red, green and blue-colored potato starch grains, and the emulsion was reversal processed to give a positive image of the scene which appeared colored when viewed by light transmitted through the plate. The process allowed the formation of a colored photograph without the chemical complexity of later photographic methods.
The Dufaycolor process (initially the Dioptichrome plate, L.Dufay, 1909) used a regular array of red, green and blue dyed patches and lines printed on a gelatin layer in conjunction with a reversal-processed black-and-white emulsion system, which similarly gave a colored image of the scene when viewed by transmitted light.
Polavision (Edwin Land and the Polaroid Corporation, 1977) was a color movie system employing a rapid and convenient reversal processing method on a black-and-white emulsion system coated above an array of red, green and blue stripes, which gave a colored projected image. It was marketed as a still color transparency system called Polachrome in 1983.
These methods suffered a number of disadvantages. The images were best viewed by passing light through the processed film or plate, and the image quality was not sufficient to allow high quality prints to be prepared from them, due to the coarse nature of the Autochrome and Dufaycolor filter arrays, and the coarse nature of the positive silver image in the Polavision and Polacolor systems. The regular array patterns were complicated and expensive to manufacture. In addition, the films which used regular or repeating filter arrays were susceptible to color aliasing when used to photograph scenes with geometrically repeating features.
U.S. Pat. No. 4,971,869 discloses a film with a regular repeating filter array which claims to be less susceptible to aliasing problems. The film comprises a panchromatic photographic emulsion and a repetitive pattern of a unit of adjacent colored cells wherein at least one of the cells is of a subtractive primary color (e.g. yellow, magenta or cyan) or is of a pastel color. Scene information can be extracted from the developed film by opto-electronic scanning methods.
EP 935 168 discloses a light sensitive material comprising a transparent support having thereon a silver halide emulsion layer and a randomly arranged color filter layer comprising colored resin particles. The document also discloses exposing, processing and electro-optically scanning the resultant image in such a film and reconstructing the image by digital image processing.
Color photographic films which comprise a color filter array and a single image recording layer or layer pack have the advantage of rapid and convenient photographic processing, as the single image recording layer or layer pack can be processed rapidly without the problem of mismatching different color records if small variations occur in the process. A small change in extent of development for example will affect all color records equally. Exceptionally rapid processing is possible using simple negative black-and-white development, and if suitable developing agents are included in the coating, the photographic response can be remarkably robust or tolerant towards inadvertent variations in processing time or temperature. Developing agents suitable for including in the coating, and a preferred way of incorporating them, are disclosed in U.S. Pat. No. 5,804,359.
Problem to be solved by the Invention
It is desirable that the method of manufacturing the color filter array be of comparatively low cost. Known methods of making regular filter arrays, such as those used for Dufaycolor or Polachrome films, are complex and costly, involving several sequential applications of materials to the film. Known methods of making random filter arrays, such as those used for Autochrome film and that described in EP 935 168 also involve complex operations, including separating and grading or sizing the colored particles of starch or resin respectively, dispersing them in a coating medium, coating and drying and then calendaring the coated layer to flatten the particles.
An economical method of manufacturing a random color filter array is described in co-pending application Ser. No. 09/808,844, reference 11574, by the applicant, filed on the same day as the present application. The method uses existing photographic manufacturing methods such as oil-in-water dispersion and photographic coating, so new equipment is not required. There is no need to separate or isolate the color elements, little or no volatile organic solvents need to be evaporated or recovered, and the only drying step is the normal drying of a coated photographic film. No calendaring step is needed as the fluid filter elements become flatter as the coating dries, as depicted in the schematic FIGS. 1 and 2 of that application. This results in a simplified and economical production process when compared with the Autochrome method or the method described in EP 935 168.
In the case of color filter arrays of the types described in the co-pending application Ser. No. 09/808,844, reference 11574, and in EP 935 168, which contain randomly disposed colored particles or droplets, it has been found that improved color information may be recorded if the space in between the randomly disposed colored particles or droplets is filled with a further color, when viewed from a direction normal to the plane of the array. For example, if there are red and blue randomly disposed colored particles or droplets, the space between them may be colored green. This is illustrated schematically in
FIG. 1
of the present application. In EP 935 168, an example is given (Example 2) in which the gelatin binder between the colored resin particles is colored by addition of a yellow dye, corresponding to Color 3 in
FIG. 1
below.
SUMMARY OF THE INVENTION
According to the present invention there is provided a color filter array comprising a water soluble or water dispersible binder, at least two color classes of water immiscible colored filter elements and a further color class of water immiscible colored filter elements the mean diameter of which is less than the mean diameter of the at least two color classes of elements.
Preferably the larger color class of elements have a mean diameter of between 2 and 20 micrometers and the further color class of elements have a mean diameter of less than 0.3 micrometers.
Advantageous Effect of the Invention
Color filter arrays according to the invention, in which the space between the randomly disposed colored particles or droplets is filled with a further color class of small water-immiscible colored filter elements or particles, which may be supported in a polymeric binder, offer improved performance over an array in which the polymeric binder is colored with a soluble dye.
The physical integrity of the array is improved. Dyes can be displaced from their binding sit
Eastman Kodak Company
McPherson John A.
Pincelli Frank
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