Radiation sensitive composition comprising copolymer of glycidyl

Radiation imagery chemistry: process – composition – or product th – Diazo reproduction – process – composition – or product – Composition or product which contains radiation sensitive...

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430942, 430945, 430187, 430302, 430494, 430524, 430533, 430189, 430627, 427 431, 427 531, 20415918, 20415923, 430 1, G03C 170, G03C 154, G03C 186, G03C 194

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042104491

ABSTRACT:
Copolymers of glycidyl methacrylate and allyl glycidyl ether having pendant epoxy groups, having an inherent viscosity of at least about 0.25, preferably within the range of about 0.25 to about 0.38, and an epoxy equivalent of at least about 0.65 epoxide equivalent per 100 g. of polymer are provided which upon admixture with a radiation-sensitive aryldiazonium salt provide compositions which exhibit improved sensitivity, curing rates and other properties. Articles for recording and storing information from a laser source and other articles such as microfilm are derived from such compositions by subjecting a coated substrate to an energy source of sufficient intensity to decompose the radiation-sensitive catalyst and thus effect polymerization via the epoxy groups of the copolymer.

REFERENCES:
patent: 3074869 (1963-01-01), Workman
patent: 3205157 (1965-09-01), Licori
patent: 3396019 (1968-08-01), Uhlig
patent: 3708296 (1973-01-01), Schlesinger
patent: 3752669 (1973-08-01), Abolafia
patent: 3790385 (1974-02-01), Steppah et al.

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