Radiation induced grafting of polyorganosiloxanes to fluoroelast

Coating processes – Direct application of electrical – magnetic – wave – or... – Polymerization of coating utilizing direct application of...

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428 368, 428421, 428447, 355285, 522 99, C08J 704

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active

055872085

ABSTRACT:
A method of making a low surface energy material such as a fuser member comprising providing a shaped fluoroelastomer, preparing a solvent solution of a polyorganosiloxane having reactive functionality and the formula: ##STR1## where R is an alkyl, alkenyl or aryl group having less than 19 carbon atoms or an aryl group substituted with an alkyl or alkenyl group having less than 19 carbon atoms, the functional group A is epoxy, vinyl, acrylic, allylic or methacrylic and n is 2 to 350, contacting the fluoroelastomer with the solution to form at least a thin coating of the polyorganosiloxane on said fluoroelastomer and exposing the coated fluoroelastomer to a level of radiation to form a thin surface layer of the polyorganosiloxane grafted to said fluoroelastomer.

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