Radiation-curable composition for restorative and/or protective

Radiation imagery chemistry: process – composition – or product th – Imaged product – Structurally defined

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20415913, 20415916, 20415919, 252600, 430 18, 430140, 430432, 430463, 430523, 430531, 430532, 430535, 430536, 430272, 430284, 430449, 430906, 430938, 430961, G03C 176, G03C 526

Patent

active

043339980

ABSTRACT:
Radiation-curable compositions useful for restorative and/or protective treatment of photographic elements are comprised of an acrylated urethane, an aliphatic ethylenically-unsaturated carboxylic acid, a multifunctional acrylate, and a siloxy-containing polycarbinol. Photographic elements, such as still films, motion picture films, paper prints, microfiche, and the like, are provided with a protective overcoat layer which is permanently bonded to the element, and serves to protect it from abrasion and scratches, by coating the element with the radiation-curable composition and irradiating the coating to bond it to the element and cure it to form a transparent, flexible, scratch-resistant, cross-linked polymeric layer. The protective overcoat layer can be applied to the image-bearing side of the element or to the support side of the element or to both sides. The radiation-curable composition can also be used as a restorative composition in the treatment of photographic elements which have scratches, abrasion marks, and the like, which impair the appearance or projection capabilities of the element. In use as a restorative composition, the radiation-curable composition can be applied locally in the region of the defects only, to effectively eliminate them and restore the element to a substantially defect-free condition, or it can be applied over the entire surface of the element to both eliminate the defects and form a protective overcoat layer that is capable of providing protection against subsequent scratching or abrasion.

REFERENCES:
patent: 4082634 (1978-04-01), Chang
patent: 4092173 (1978-05-01), Novak et al.
patent: 4130708 (1978-12-01), Friedlander et al.
patent: 4171979 (1979-10-01), Novak et al.
patent: 4248958 (1981-02-01), Faust
Dow Corning Corporation product bulletin entitled, "Information About Silicone Surfactants For Urethanes," Aug. 1968.
Dow Corning Corporation product bulletin entitled, "Organo-functional Silicone Fluids--Silicone Polycarbinols".

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