Quinuclidine derivatives

Details Quinuclidine derivatives Quinuclidine derivatives

1974-05-02

1976-01-06

Todd, G. Thomas

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D45302

Patent

active

039311937

ABSTRACT:
Quinine, quinidine and analogs thereof, are prepared by reacting a 4-quinolyllithium compound with a 4,5-erythro-5-ethyl(or vinyl)-quinuclidine-2 .xi.-carboxaldehyde or the corresponding quinuclidine-2-carboxylic acid alkyl ester. Also described, inter alia, is the preparation of a 4,5-erythro-5-ethyl(or vinyl)-quinuclidine-2 .xi.-carboxaldehyde, and a 4,5-erythro-5-ethyl(or vinyl)-quinuclidine-2 .xi.-carboxylic acid and esters thereof. The end products are useful as anti-malarial and antiarrhythmic agents.

REFERENCES:
chem. Abstracts, 53: 6278c, (1959).
Chem. Abstracts, 54: 22641a, (1960).

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