Quasi-liquid crystals

Organic compounds -- part of the class 532-570 series – Organic compounds – Azoxy

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534577, 534611, 534752, 534787, 548409, 548411, 25229901, 25229961, 252586, G02B 523, C09K 1934, C09K 1954, C07D491107

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049279173

ABSTRACT:
There are provided compounds which give quasi-liquid crystals, which comprise a mesogenic group, which can contain bridging groups, a bridging group and a spiropyran moiety having a 2H pyran ring, a terminal group being attached to the mesogenic group. The mesogenic group contains two aromatic, heterocyclic or cycloaliphatic ring structures. The compounds are prepared by a coupling reaction of mesogenic groups with a spiropyran compound via a suitable bridging group. There is provided a process for producing quasi-liquid crystalline (QLC) films which are useful for producing a wide variety of devices based on the optical non-linearity of generation of second harmonics by such films. Such devices can also be based on ferroelectric, pyroelectric, piezoelectric effects and photoactivity of such oriented QLC films.

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patent: 4405733 (1984-09-01), Williams et al.
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Schnuriger et al, CA 86:88850, (1977).
Kobayashi, CA 92:197581, (1980).
Otkuba et al., CA 97:23011, (1982).
"Quasi-Liquid Crystals", By: Felix Shvartsman et al, reprinted from Nature, vol. 309, No. 5969, pp. 608-611, June 14, 1984.
"Quasi-Crystals, Growth from Photochromic Spiropyrans on Irridation in a Constant Electric Field", By: V. A. Krongauz et al, Reprinted from The Journal of Physical Chemistry, vol. 82, No. 23, 1978.
"Investigation of the Quasi-Liquid Crystal Structure", By: Felix P. Shvartsman et al, Reprinted from The Journal of Physical Chemistry, 1985, 89, 3941-3946.

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