Quantum-splitting fluoride-based phosphors, method of...

Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides

Reexamination Certificate

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C313S467000, C313S468000, C313S486000, C313S487000, C252S30140R, C252S30140P, C252S301500, C252S30140F

Reexamination Certificate

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10917127

ABSTRACT:
A quantum-splitting phosphor has a formula of ADF5:Pr3+, wherein A is at least one alkaline-earth metal and D is at least one Group-IIIB metal. The phosphor is made in a solid-state method without using hazardous HF gas. The phosphor can be used alone or in conjunction with other phosphors in light sources and displays wherein it can be excited by VUV radiation, and increase the efficiency of these devices.

REFERENCES:
A. P. Vink et al., “Photon Cascade Emission in SrAlF5:Pr3+”, J. Phys., Condens. Matter., vol. 14, 8889-8899 (2002).
E. van der Kolk et al., “Luminescence Exciation Studyb of the Higher Energy States of Pr3+ and Mn2+ in SrAlF5, CaAlF5, and NaMgF3”, J. Appl. Phys., vol. 95, No. 12, 7867-7872 (2004).
F. Kubel, “The Crystal Structures of SrAlF5 and Ba0.43(1)Sr0.57(1)AlF5”, Z. Anorg. Allg. Chem., vol. 624, 1481-1486 (1998).
E. van der Kolk et al., “Vacuum Ultraviolet Excitation and Quantum Splitting of Pr3+ in LaZrF7 and α-LaZr3F15”, Optics Comm., vol. 197, 317-326 (2001).

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