Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1972-12-20
1976-03-16
Weinberger, Lorraine A.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
C07C 5133, C07C 6326
Patent
active
039446018
ABSTRACT:
Phthalic acids of improved quality are obtained direct from oxidation of xylenes with molecular oxygen in oxidation zone having less than one equivalent of strongly acidic inorganic acid per equivalent of catalyst metal present in addition to a liquid phase acetic acid solution of one or more heavy metal oxidation catalyst and bromine releasing bromide compound. Particularly useful inorganic acids are those having ionization constant K.sub.A greater than 1.0 .times. 10.sup.-.sup.2, e.g. hydrobromine, nitric, sulfuric and phosphoric acids. Such quality improvement is manifested by decreased aldehydic acid and toluic acid impurity contents.
REFERENCES:
patent: 3047612 (1962-06-01), Pennington et al.
patent: 3075009 (1963-06-01), Keith et al.
patent: 3665030 (1972-05-01), Radzitsky et al.
Ahlers Fred R.
Gilkes Arthur G.
Kelly Richard D.
McClain William T.
Standard Oil Company
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