Quality of phthalic acids improved by strong inorganic acids

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 5133, C07C 6326

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active

039446018

ABSTRACT:
Phthalic acids of improved quality are obtained direct from oxidation of xylenes with molecular oxygen in oxidation zone having less than one equivalent of strongly acidic inorganic acid per equivalent of catalyst metal present in addition to a liquid phase acetic acid solution of one or more heavy metal oxidation catalyst and bromine releasing bromide compound. Particularly useful inorganic acids are those having ionization constant K.sub.A greater than 1.0 .times. 10.sup.-.sup.2, e.g. hydrobromine, nitric, sulfuric and phosphoric acids. Such quality improvement is manifested by decreased aldehydic acid and toluic acid impurity contents.

REFERENCES:
patent: 3047612 (1962-06-01), Pennington et al.
patent: 3075009 (1963-06-01), Keith et al.
patent: 3665030 (1972-05-01), Radzitsky et al.

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