Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Patent
1985-04-04
1989-05-02
Hollrah, Glennon H.
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
564 2, 564478, 564480, 564497, 564498, 564512, 502208, C07C 8506
Patent
active
048270377
ABSTRACT:
Process for the improvement of the quality of polyalkylene polyamines prepared by the reaction of (i) ammonia and/or an alkyleneamine compound having at least two amino groups and an alkanolamine compound having at least one amino group in the presence of a catalytically effective amount of a metal acid phosphate and at a temperature and pressure sufficient to form the polyalkylene polyamine. When the polyalkylene polyamines, being produced by the process, have a dark black color which is measured as a Gardner Color Standard Number of at least 15 on the Gardner Color Scale and/or have a burnt or scorched odor, the inclusion of a sufficient amount of hydrogen with the ammonia and/or alkyleneamine compound and the alkanolamine compound, so that the hydrogen is in contact with the ammonia and/or alkyleneamine and alkanolamine in the reaction zone, will abate the burnt or scorched odor of the polyalkylene polyamines being produced and will lower the Gardner Color Standard Number of the polyalkylene polyamines being produced to 10 or below on the Gardner Color Scale. The best results are obtained by introducing the hydrogen along with the reactants into the reactor. By always using the hydrogen addition, one can abate or eliminate the poor quality problem from arising by thereby avoiding the production of such black, malodoriferous polyalkylene polyamines.
REFERENCES:
patent: 3714259 (1973-01-01), Lichtenwalter et al.
patent: 3723529 (1973-03-01), Pitts et al.
patent: 3819710 (1974-06-01), Jordan
patent: 4123462 (1978-10-01), Best
patent: 4404405 (1983-09-01), Winters
patent: 4463193 (1984-07-01), Johnson et al.
Coon Gerald L.
Hollrah Glennon H.
Treanor S.
Union Carbide Corporation
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