Coating processes – Direct application of electrical – magnetic – wave – or... – Polymerization of coating utilizing direct application of...
Patent
1998-07-27
2000-04-04
King, Roy V.
Coating processes
Direct application of electrical, magnetic, wave, or...
Polymerization of coating utilizing direct application of...
427515, 427535, 42725518, 4273977, 427534, C08F 246
Patent
active
060458771
ABSTRACT:
Provided are pyrolytic chemical vapor deposition techniques for producing thin silicone-like films by way of processes that eliminate electron impact, ion bombardment, and UV irradiation events. To form a silicone film on a surface of a structure in accordance with the invention, the structure surface is exposed to a substantially electrically neutral reactive gaseous phase that includes organosilicon molecular fragments, while the structure surface is maintained substantially at a temperature lower than that of the reactive gaseous phase. An organosilicon compound is exposed to a pyrolyzing environment, where the conditions of the pyrolyzing environment are characterized as producing, in the vicinity of the structure surface, a substantially electrically neutral reactive gaseous phase that includes organosilicon molecular fragments. The structure surface is maintained substantially at a temperature lower than that of the pyrolyzing environment. A plasma environment can be provided simultaneously with the pyrolyzing environment, and can be further provided before or after the pyrolyzing environment. Silicone films of the invention are mechanically robust, environmentally stable, and photosensitive.
REFERENCES:
patent: 3319311 (1967-05-01), Mutter
patent: 4085248 (1978-04-01), Zehender et al.
patent: 4435476 (1984-03-01), Phillips et al.
patent: 4546008 (1985-10-01), Saitoh et al.
patent: 4894254 (1990-01-01), Nakayama et al.
patent: 5160544 (1992-11-01), Garg et al.
patent: 5298290 (1994-03-01), Jost et al.
patent: 5320875 (1994-06-01), Hu et al.
patent: 5439780 (1995-08-01), Joshi et al.
patent: 5521126 (1996-05-01), Okamura et al.
patent: 5576068 (1996-11-01), Caburet et al.
patent: 5888591 (1999-03-01), Gleason et al.
Chawla, "Evaluation of plasma polymerized hexamethylcyclotrisiloxane biomaterials towards adhesion of canine platelets and leucocytes," Biomaterials, vol. 2, pp. 83-88, Apr. 1981.
Sakata et al., "Plasma Polymerized Membranes and Gas Permeability. II," Journal of Applied Polymer Science, vol. 31, pp. 1999-2006, 1986. No month data.
Fukui et al., "Surface modification of pigments by the chemical vapour deposition of cyclic dimenthylsiloxane," Jocca-Surface Coatings Int'l, V. 75, No. 10, pp. 411-412, 414-418, Oct. 1992.
Tajima, et al., "Characterization of Plasma Polymers from Tetramethylsilane, Octamethylcyclo-tetrasiloxane, and Methyltrimethoxysilane," Journal of Polymer Science: Part A: Polymer Chemistry, vol. 25, pp. 1737-1744, 1987. No month data.
Kwan, "Hot-Filament Chemical Vapor Deposition of Selectively Deposited Diamond and Silicone Thin Films," Massachusetts Institute of Technology Ph.D. Thesis, Sep., 1997. No page number.
Gleason Karen K.
Kwan Michael C.
King Roy V.
Lober Theresa A.
Massachusetts Institute of Technology
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