Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...
Patent
1995-11-22
1997-03-11
Shah, Mukund J.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heterocyclic carbon compounds containing a hetero ring...
546 11, 546211, C07D40100, C07F 108, C07F 306
Patent
active
056103050
ABSTRACT:
Novel pyrazole-containing compounds useful as light-stabilizers for polymers, their Ni, Zn, Cu, and Co metal complexes, and methods for the synthesis of such complexes are provided. The compounds include a hindered amine light stabilizer (HALS) such as a substituted piperidine, thereby incorporate the properties of UV absorbers and redical scavengers. The compounds are of the formulas I and II, ##STR1## where R.sub.1 is phenyl, R.sub.2 is methyl, X is oxygen or sulphur, Z is oxygen or N-aryl, and R.sub.3 is hydrogen, alkyl, a derivative of carboxyacryloyl or carboxybenzoyl or a derivative of pyrazole. The compounds and their metal complexes are highly compatible with various polymers, thermostable, and retain their photostability under conditions of continuous and intensive irradiation. Methods for the synthesis of metal complexes include the reaction of: (a) a compound with metal acetate; or (b) a metal complex with anhydride or a pyrazole derivative.
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Azran Jack
Kvitko Idel Y.
Friedman Mark M.
Rao Deepak R.
Shah Mukund J.
UV Stab Ltd.
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