Purified monoammonium phosphate process

Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing

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423313, C01B 2528

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043259278

ABSTRACT:
A method of producing purified monoammonium phosphate from wet process phosphoric acid and ammonia is provided. The ammoniation takes place in two stages, the acid being ammoniated in the first stage to a pH between about 1.5 and 2.5. This mixture is allowed to age after which the mixture is ammoniated to a pH between about 4 and 5. An impurity-containing precipitate is formed in the first and second stages of ammoniation that is easily filterable from the monoammonium phosphate solution derived from the second ammoniation stage.

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patent: 3667904 (1972-06-01), Roche et al.
patent: 3974263 (1976-08-01), Crerar et al.
Ando et al, "Ammoniation Reactions of Wet-Process Phosphoric Acid," Chuo University, Japan.
Potts et al, "Liquid Fertilizers from Wet-Process Phosphoric Acid," Chemical Engineering Progress, (vol. 58, No. 9), (Sep. 1962), pp. 89-93.
Claim 1 of U.S. Pat. No. 4,117,089.

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