Chemistry of inorganic compounds – Halogen or compound thereof – Binary fluorine containing compound
Patent
1990-03-30
1994-06-28
Lewis, Michael L.
Chemistry of inorganic compounds
Halogen or compound thereof
Binary fluorine containing compound
62 85, 62119, C01G 4104
Patent
active
053244982
ABSTRACT:
A process is provided for purifying liquid tungsten hexafluoride containing volatile and non-volatile impurities. The process comprises the steps of evaporating tungsten hexafluoride from non-volatile impurities dissolved in liquid tungsten hexafluoride and condensing the evaporated tungsten hexafluoride. The condensed tungsten hexafluoride is subjected to freezing to solidify the tungsten hexafluoride. Volatile impurities are then evacuated from the solid tungsten hexafluoride. Thereafter, the solid tungsten hexafluoride is thawed to liquid tungsten hexafluoride to release trapped volatile impurities and then heated to a temperature above the boiling point of tungsten hexafluoride under pressure in a closed container. The volatile impurities dissolved in the thawed tungsten hexafluoride are removed and collected above the thawed tungsten hexafluoride and vented into an evacuated space.
REFERENCES:
patent: 3992159 (1976-11-01), Mitchell
patent: 3995011 (1976-11-01), Jache et al.
patent: 4339350 (1982-07-01), Pellegrini, Jr. et al.
Almond Don A.
Doane Robert E.
Streusand Barry J.
Bandgap Chemical Corporation
Bolam Brian M.
Lewis Michael L.
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