Purification of halide

Chemistry of inorganic compounds – Halogen or compound thereof – Hydrogen halide

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55 71, 55 73, 55 75, C01B 707, B01D 5300

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active

045579210

ABSTRACT:
A process for the removal of hydrogen halides including HCl and HF, and/or sulfur dioxide from silicon tetrafluoride. Contaminated gaseous silicon tetrafluoride is passed through a column of zeolite preferably in the hydrogen cation form so as to permit recovery of silicon tetrafluoride containing less than about 10% of the original contamination levels. Acid-stable zeolite materials suitable for the process of the invention are subjected to a flow of hot gases to permit regeneration of the column for use in a semicontinuous process.

REFERENCES:
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patent: 3682594 (1972-08-01), Fish
patent: 3702886 (1972-11-01), Argauer
patent: 3709979 (1973-01-01), Chu
patent: 3832449 (1974-08-01), Rosinski
patent: 3953587 (1976-04-01), Lee et al.
patent: 4016245 (1977-04-01), Plank
patent: 4046859 (1977-09-01), Plank
patent: 4076842 (1978-02-01), Plank
The Encyclopedia of Chemistry, 3rd Ed., Ed. by Clifford A. Hampel & Gessner G. Hawley, Van Nostrand Reinhold Co., 1973, pp. 685-687.
"American Mineralogist," vol. 28, p. 545, 1943, Dec. 1943.
Zeolon.RTM. Molecular Sieves, Norton, 1982.
Adsorption by Dehydrated Zeolite Crystals in Zeolite Molecular Sieves, D. W. Breck, Riley Interscience Publishers, 1974, pp. 607-611, 616, 618-619, and 625-627.

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