Purification of gases

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon monoxide component

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423220, 423230, 423248, 4234182, 4234371, 4235801, 252373, C01B 3118, C01B 300, C01B 1716, C01B 3120, C01B 502, C07C 102

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060746211

ABSTRACT:
Carbon monoxide is removed from air prior to cryogenic separation of oxygen and nitrogen. Feed air is compressed and the heat of compression is used without further heating to drive catalytic oxidation of CO to CO.sub.2 over a Pd and/or Pt on alumina catalyst followed by adsorption of water initially present and then either adsorption of hydrogen or oxidation of hydrogen to water and its removal by adsorption, along with carbon dioxide.

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Forster, et al., "Spectroscopic investigations on sorption and oxidation of carbon monoxide in transition metal ion-exchanged zeolites A: Studies on cobalt, nickel and copper forms" Zeolites, 1987, vol. 7, Nov 517-521, Anderson, H. C. and Green, W. J., Ind. Eng. Chem. 53, 645 (1961).

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