Purification of crude acrylic acid

Distillation: processes – separatory – Convective distillation with normally gaseous medium – e.g. – air

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203 73, 203DIG21, 562600, B01D 334, C07C 5144, C07C 5704

Patent

active

041994108

ABSTRACT:
A process for purifying crude acrylic acid characterized in that high-purity purified acrylic acid containing little or no low boiling aldehydes is obtained by rectifying a crude acrylic acid consisting essentially of acrylic acid and containing low boiling substances such as acetaldehyde, acrolein, water and acetic acid and/or high boiling substances such as maleic acid, phenol, benzaldehyde and acrylic acid dimer, thereby removing said low boiling substances and then high boiling ones, and then stripping trace amounts of remaining low boiling aldehydes with an inert gas such as nitrogen or air at a liquid to gas molar ratio of 2 to 20.

REFERENCES:
patent: 3406100 (1968-10-01), Karafian
patent: 3513632 (1970-05-01), Hess et al.
patent: 3781193 (1973-12-01), Sennewald et al.
patent: 3859175 (1975-01-01), Ohrui et al.
patent: 3932500 (1976-01-01), Duembgen et al.

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