Purification of cis-olefins

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By addition of extraneous agent – e.g. – solvent – etc.

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585866, 585868, C07C 717

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active

049408313

ABSTRACT:
A method for purifying a cis-olefin formed by alkylating a sulfonate ester comprising mixing the reaction formed by alkylating a sulfonate ester with an acid solution, separating said acid solution, and mixing the resultant purification product with a C.sub.1 -C.sub.4 alcohol and optionally a base followed by separation and distillation, or passing said reaction mixture through a silica gel and collecting the cis-olefin fraction.

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"Comprehensive Organic Chemistry", Pergamon Press, New York, vol. 3, pp. 320-322.
"Sulfinic Acid Catalyzed Isomerization of Olefins", J. Org. Chem. 41: p. 791 (1976).
"The Reaction Between Sulfochlorides and Organomagnesium Halides", Gilman et al, pp. 3501-3508, Nov. 1929.
"The Constitution of Some Bacterial Casotenoids and their Bearing on Biosynthetic Problems", Jensen, 1962, p. 106.

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