Purification of alkali metal chlorides and bromides

Chemistry of inorganic compounds – Halogen or compound thereof – Binary compound containing metal

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C01D 314, C01D 320, C01D 304, C01D 310

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039694917

ABSTRACT:
We have discovered that alkali halides may be purified, particularly of trace anionic and cationic impurities, by scrubbing a melt of the alkali halide with gaseous nascent halogen. The halide radical of the gaseous nascent halogen preferably corresponds to the halide radical of the alkali halide. The purified material may then be used to form single crystals from which laser windows may be produced.

REFERENCES:
patent: 3826817 (1974-07-01), Pastor et al.
McPherson and Henderson Book "A Course in General Chem.," 3rd Ed., 1927, pp. 229, 230, Ginn & Co., N.Y.
Lawson & Nielsen Book "Preparation of Single Crystals," 1958, pp. 57, 58, Butterworths Scient. Pub., London.

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