Proton conductive solid polymer electrolyte and method for...

Chemistry: electrical current producing apparatus – product – and – With pressure equalizing means for liquid immersion operation

Reexamination Certificate

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C528S335000, C528S337000, C528S341000, C528S344000, C528S347000, C528S350000, C528S373000, C528S377000, C528S390000, C528S391000, C528S423000, C429S309000, C429S310000, C429S324000

Reexamination Certificate

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07045241

ABSTRACT:
A monomer to produce polybenzimidazole is dissolved in polyphosphoric acid. For example, polysulfated phenylene sulfonic acid (acidic group-possessing polymer) is further dissolved in this solution. In this procedure, the acidic group-possessing polymer and the monomer are adsorbed to one another in accordance with the acid-base interaction. When the monomer is polymerized, for example, by means of dehydration polymerization in this state, then polybenzimidazole is synthesized, and the polybenzimidazole and the acidic group-possessing polymer are compatibilized with each other to produce a compatibilized polymer. When the compatibilized polymer is deposited as a solid, and the solid is separated from polyphosphoric acid, then the compatibilized polymer is obtained. A proton conductive solid polymer electrolyte as a final product is manufactured by forming the compatibilized polymer to have a predetermined shape.

REFERENCES:
patent: 5525436 (1996-06-01), Savinell et al.
patent: 5906716 (1999-05-01), Mertesdorf et al.
patent: 6124060 (2000-09-01), Akita et al.
patent: 19817374 (1999-10-01), None
patent: 19817374 (1999-10-01), None
patent: 2000-38472 (2000-02-01), None
patent: 2001-160407 (2001-06-01), None
patent: WO 00/27513 (2000-05-01), None
patent: WO 00/27513 (2000-05-01), None
patent: WO 01/94450 (2001-12-01), None
patent: WO 01/94450 (2001-12-01), None
patent: WO 01/94450 (2001-12-01), None
“Synthesis and characterization of novel acid-base polymer blends for application in membrane fuel cells”; Solid State Ionics (1999), vol. 125, pop. 243-249.

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