Protected amino-functional initiators and amino-terminated polym

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 29, 526 54, 526 56, C08F 448, C08F 812, C08F 1208, C08F 3614

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active

040150615

ABSTRACT:
N,N-bis(trialkylsilyl) amino-terminated polymers are prepared by treating p-lithio-N,N-bis(trialkylsilyl) aryl amine with a diene monomer and the resulting polymers are converted to a mono- or di- primary aryl amine-ended diene polymer directly by acid hydrolysis. The amine-ended polymers may be homopolymers of a conjugated diene which contain 4 to 8 carbon atoms or copolymers of such conjugated dienes or copolymers of such a conjugated diene and a vinyl monomer.

REFERENCES:
patent: 3300465 (1967-01-01), Bayer
Rubber Chemistry Technology 42, 90; 1969, D. M. French.

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