Prostanoids and synthesis thereof

Details Prostanoids and synthesis thereof Prostanoids and synthesis thereof

1989-06-01

1991-05-07

Gerstl, Robert

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C25100

Patent

active

050138626

ABSTRACT:
Prostaglandin analogues which include a bicyclic isoxazolidine nucleus are disclosed. These analogues may be used to prepare other prostaglandins. Essential to the synthesis is intramolecular nitrone-alkene cycloaddition involving an alkenyl nitrone in which the reacting centers are separated by two carbons.

REFERENCES:
patent: 4112224 (1978-09-01), Bundy
patent: 4275213 (1981-06-01), Bundy
Padwa, J. Org. Chem. Sl 3125 (1986).

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