Prostaglandin intermediates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C17700

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active

048662054

ABSTRACT:
New optically active intermediates and processes thereto are provided for use in synthesizing therapeutically active prostaglandins of the formula: ##STR1## wherein R.sup.1 is hydrogen or lower alkyl; from a compound of the formula: ##STR2## wherein R.sup.1 is as above and R.sup.2 is hydrogen or a carboxy blocking group convertible to an acid by hydrolysis.

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patent: 4154963 (1979-05-01), Kienzle
Overman et al., Tet. Letters 4, 321-24 (1979).
Vasil'eva et al., J. Gen. Chem. USSR, 52, 2346-47 (1982).
Grieco et al., J. Am. Chem. Soc. 102, 7587-88 (1980).
Grieco et al., J. Org. Chem. 46, 5005-07 (1981).
Shotnicki et al., J. Medicinal Chem. 20:1551-1557 (No. 12) (1977).
Corey, E. J., J. Amer. Chem. Soc, 95:20 (1973), pp. 6832-6833.

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