Propylene diene copolymerized polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S160000, C526S165000, C526S170000, C526S339000

Reexamination Certificate

active

07005491

ABSTRACT:
A method of lowering MFR response of a high melt flow rate polymer producing metallocene catalyst is provided. The method includes contacting the metallocene catalyst with a sufficient quantity of α,ω-diene monomer such that when the catalyst composition is contacted with polymerizable reactants under suitable polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 19. Hydrogen and ethylene may also be present in the polymerization. Additionally a catalyst composition is provided which includes a high melt flow rate polymer producing metallocene catalyst and a sufficient quantity of α,ω-diene monomers such that when the catalyst composition is contacted with a monomer under polymerization conditions, the resulting polymer has an MFR rate in the range of 0.1 to 19.

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