Proppants and anti-flowback additives made from sillimanite...

Earth boring – well treating – and oil field chemistry – Well treating

Reexamination Certificate

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C507S209000, C507S904000, C507S906000, C501S141000

Reexamination Certificate

active

07737091

ABSTRACT:
Spherical and rod-shaped proppants and anti-flowback agents made from sillimanite minerals possess high strength and high conductivity. The sillimanite minerals may be selected from the group consisting of kyanite, sillimanite, and andalusite and may be used alone or in combination with other materials, such as bauxite, kaolin, meta-kaolin, pure or technical grade alumina (about 98%-99.9% alumina by weight), alumina-containing slag, zirconia, silica, iron, alkali elements (such as calcium, magnesium, and sodium), and virtually any other mineral containing alumina. The starting material may optionally be milled to achieve better compacity and crush resistance in the final proppant or anti-flowback agent. A fracturing fluid may comprise the rods or spheres alone, or in combination with each other or other proppants or anti-flowback agents of different shapes.

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patent: WO 2008/094069 (2008-08-01), None
Marie-Laure Bouchetou, Jean-Pierre Ildefonse, Jacques Poirier, Pierre Daniellou,Mullite Grown from Fired Andalusite Grains: The Role of Impurities and of the High Temperature Liquid Phase on the Kinetics of Mullitization and Consequences on Thermal Shocks ResistanceCeramics International 31 (2005) 999-1005; Elsevier Ltd and Techna Group S.r.I.
Srikrishna, K., et al., “Kaolinite-mullite reaction series: a TEM study”, Journal of Materials Science, vol. 25, Jan. 1990, pp. 607-612.
Blair, G.R., et al., “Kaolinite-Mullite Series: Firing vs. Reactive-Hot Pressing”, Journal of Thermal Analysis, vol. 4, Jan. 1972, pp. 311-322.
International Search Report issued Jun. 30, 2009, for counterpart PCT Application No. PCT/IB2008/003074.
Written Opinion of the International Searching Authority issued Jun. 30, 2009, for counterpart PCT Application No. PCT/IB2008/003074.

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