Production of transparent cationically-homogeneous nanostructure

Chemistry of inorganic compounds – Rare earth compound

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423592, 423593, 423625, C01F 1700, C01F 700

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active

060663057

ABSTRACT:
This invention relates to a generic process for producing a refractory oxide which comprises reacting liquid water with: at least one metal fluoride reactant; or at least one metal fluoride reactant and at least one metal oxide reactant; or at least one metal oxide reactant and an aqueous hydrogen fluoride solution, to produce either a colloidal mixture or a solution; drying either the colloidal mixture or solution; heating the dried product to produce a solid state metal hydroxyfluoride; heating the hydroxyfluoride to a temperature at which it chemically decomposes into a cationically-homogeneous and nanostructured solid state metal oxyfluoride; and performing one of the following heating steps: (i) to a solid state decomposition-temperature where the oxyfluoride chemically decomposes into a refractory oxide; or, (ii) to a molten state decomposition-temperature where the oxyfluoride chemically decomposes into a refractory oxide; or, (iii) to a vapor state decomposition-temperature where the oxyfluoride chemically decomposes into a refractory oxide.

REFERENCES:
patent: 3941874 (1976-03-01), Payne
patent: 4402924 (1983-09-01), McVicker et al.
patent: 5558847 (1996-09-01), Kaaber et al.

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