Production of thermoplastic resin having high impact resistance

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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525303, 525316, C08K 510, C08L 5104, C08F27904

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active

052816460

ABSTRACT:
In a process for producing a thermoplastic resin by emulsion polymerization using a conjugated diene rubber, an aromatic vinyl compound and a vinyl cyanide compound, and by successive flocculation and direct pelletizing, the direct pelletizing is effected in the presence of a phenolic compound represented by ##STR1## wherein R.sup.1 and R.sup.4 are each hydrogen or methyl, and R.sup.2 and R.sup.3 are each an alkyl of 1 to 9 carbon atoms. The use of the phenolic compound is effective to prevent the resin from thermal deterioration during the direct pelletizing, thereby producing the thermoplastic resin excellent in properties such as impact resistance.

REFERENCES:
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patent: 5047461 (1991-10-01), Takata et al.
patent: 5128398 (1992-07-01), Sasaki et al.
Chemical Abstracts, vol. 107, No. 12, Sep. 21, 1987, Columbus, Ohio USA, K. Motomatsu et al., "Low-temperature impact-resistant resin composition with improved heat resistance and pigment dyeability", p. 38, col. 1, abstract No. 97 658y & JP-A-61-258 856.
Chemical Abstracts, vol. 107, No. 4, Jul. 27, 1987, Columbus, Ohio, USA. K. Motomatsu et al., "Resin compositions with improved heat resistance and pigment dyeability", p. 65, column 1, abstract No. 24 613f & JP-A-61-241 347.
Chemical Abstracts, vol. 107, No. 10, Sep. 7, 1987, Columbus, Ohio, USA, K. Motomatsu et al., "Impact-resistant resin compositions with improved heat resistance and pigment dyeability", p. 44, col. 2, abstract No. 78 902t & JP-A-61-246 243.
Chemical Abstracts, vol. 108, No. 6, Feb. 8, 1988, Columbus, Ohio USA, T. Namitsuka et al., "Diene rubber compositions for high-impact polystyrene", p. 46, col. 2, abstract No. 39 070w & JP-A-62-153 329.

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