Production of tetrahydrofuran from 1,4-butanediol

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C502S217000, C502S349000

Reexamination Certificate

active

07465816

ABSTRACT:
Provided is a method for the production of tetrahydrofuran (THF) from 1,4-butanediol (BDO) using a zirconium sulfate (Zr(SO4)2.nH2O) catalyst. The method of the present invention can achieve high-yield production of tetrahydrofuran via a simple and low-risk production process by dehydration of 1,4-butanediol in the presence of a zirconium sulfate catalyst.

REFERENCES:
patent: 4136099 (1979-01-01), Smith
patent: 4665205 (1987-05-01), Yamada et al.
patent: 6204399 (2001-03-01), Schoedel et al.
patent: 61-126080 (1986-06-01), None
Sohn et al. “Preparation of a new solid superacid catalyst, zirconium sulfaic supported on γ-alumina and activity for acid catalysis,” Catalysis Today, vol. 87, 2003, pp. 219-226.

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