Production of tertiary phosphines

Details Production of tertiary phosphines Production of tertiary phosphines

1980-09-02

1982-04-13

Sneed, Helen M. S.

Organic compounds -- part of the class 532-570 series

Organic compounds

Phosphorus containing

C07F 950

Patent

active

043249191

ABSTRACT:
The invention relates to a process for making tertiary phosphines of the general formula R.sub.3 P, in which R stands for a linear alkyl radical having 2 to 4 carbon atoms. To this end, hydrogen phosphide is reacted with linear monoolefins having 2 to 4 carbon atoms. More particularly, the tertiary phosphine which is desired to be made is dissolved in an inert solvent and PH.sub.3 and monoolefin are reacted in the solution.

REFERENCES:
patent: 2584112 (1952-02-01), Brown
patent: 2803597 (1957-08-01), Stiles
patent: 2822376 (1958-02-01), Hechenbleikner et al.

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