Production of tertiary amines

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C 8506

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active

044423063

ABSTRACT:
Tertiary amines are produced by reacting a secondary amine having identical or different substituents, in particular a readily volatile amine, with a primary or secondary monohydric or polyhydric alcohol, in particular a sparingly volatile fatty alcohol, over a copper catalyst formed directly from copper formate under the reaction conditions.

REFERENCES:
patent: 2412209 (1946-12-01), Dickey et al.
patent: 2609394 (1952-09-01), Davies et al.
patent: 2795600 (1957-06-01), Chitwood et al.
patent: 3223734 (1965-12-01), Fallstad et al.
patent: 3708539 (1973-01-01), Fenton
patent: 4145307 (1979-03-01), Krapf et al.
Russian Chemical Reviews 34, (1965), pp. 843-853.
L. Spialter, J. A. Pappalardo, "The Acyclic Aliphatic Tertiary Amines", The Macmillan Company, New York, (1965) (Cover Pages Only).

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