Chemistry of inorganic compounds – Sulfur or compound thereof – Oxygen containing
Patent
1982-08-26
1987-02-17
Straub, Gary P.
Chemistry of inorganic compounds
Sulfur or compound thereof
Oxygen containing
423522, 423529, 422161, C01B 1774, C01B 1748
Patent
active
046438874
ABSTRACT:
A feed gas mixture with SO.sub.2 partial pressure of at least about 0.5 atmosphere and an O.sub.2 :SO.sub.2 mole ratio of between about 0.7:1 and about 1:1 is passed in plug flow through a packed bed of conversion catalyst. The catalyst bed is cooled to produce a temperature profile including a first zone of increasing temperature, a second zone of substantially constant temperature and a third zone of declining temperature. The exit temperature is sufficiently low for high equilibrium conversion values. The effluent is cooled to condense liquid sulfur trioxide, while the sulfur trioxide remaining in the gas stream can be absorbed into oleum and/or sulfuric acid. Enriched oleum can be prepared by blending condensed sulfur trioxide into oleum or sulfuric acid.
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Snowball, A. F., A Cyclic Process of Sulphuric Acid Manufacture at Trail BC, Canadadiaa Chemistry & Process Industries, Dec. 1947, pp. 1110-1114.
Daley William D.
Jaffe James
Doernberg Alan M.
General Chemical Corporation
Plantamura Arthur J.
Straub Gary P.
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