Production of silane

Chemistry of inorganic compounds – Silicon or compound thereof – Binary compound

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423490, 423499, C01B 3304

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043741118

ABSTRACT:
A silicon halide such as silicon tetrafluoride is reacted with an agitated slurry of an alkali metal hydride such as sodium hydride in a liquid which includes a diaryl ether such as diphenyl ether. At elevated temperatures such as 250.degree.-260.degree. C., complete conversion of the silicon tetrahalide to silane is observed, even with contact times under two seconds.

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