Organic compounds -- part of the class 532-570 series – Organic compounds – Esters having the thiocarboxylate group – -cx- – wherein the...
Patent
1986-04-28
1987-12-08
Jiles, Henry R.
Organic compounds -- part of the class 532-570 series
Organic compounds
Esters having the thiocarboxylate group, -cx-, wherein the...
C07C15402
Patent
active
047119675
ABSTRACT:
An S-aryl S-alkyl dithiocarbonate is prepared by pyroltically isomerizing an O-aryl S-alkyl dithiocarbonate at a temperature in the range 150.degree.-600.degree. C. The reaction product may be hydrolyzed to form an arenethiol or may be further reacted with an alcohol in the presence of a basic catalyst to form an aryl thioether.
REFERENCES:
Rodd's Chemistry of Carbon Compounds, Supplement to Volume IIIA, Elsevier Scientific Publishing Company (1983), pp. 247-249.
Araki, Y., Bull. Chem. Soc. Japan, 1970, 43, pp. 252-257.
Courtaulds PLC
Jiles Henry R.
Whittenbaugh Robert C.
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