Production of polyalkenyl succinic anhydrides

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D30760

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044725884

ABSTRACT:
This invention relates to a process for producing polyalkenyl succinic anhydrides by reacting with continuous agitation a polyalkylene having a number average molecular weight of between 300 and 50,000 with maleic anhydride in a molar ratio of between 0.5:1 and 20:1 and at a temperature between 200.degree. and 250.degree. C. The feature of the process is that the maleic anhydride is added incrementally to the polybutene at such a rate that a single, homogeneous phase is maintained in the reactor throughout the duration of the reaction and the addition of maleic anhydride reactant is completed within 75% of the duration required to achieve maximum conversion of the polyalkylene of a given molecular weight. The polyalkylene derivative may for example be a polypropylene, a polybutene, a polyiso-butene or a polymer of 4-methyl pentene-1. By carrying out the reaction under these conditions the process results in a reduced amount of resin formed and enables more efficient use of maleic anhydride.

REFERENCES:
patent: 3346354 (1967-10-01), Kautsky et al.
patent: 3855251 (1974-12-01), Cahill
patent: 4282157 (1981-08-01), Van der Voort

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