Production of pheromones and fragrances from substituted and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C568S874000, C568S876000, C560S129000, C560S261000

Reexamination Certificate

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07932410

ABSTRACT:
Compounds of the formula (I)wherein R2is a branched or unbranched, saturated or ethylenically mono or di unsaturated aliphatic radical, Z is —CH2OH, —CH2OAc or —CHO, m is a whole positive integer of one or more, and Ac is an acetyl group are synthesized by a process wherein a 1-alken-3-yl alkylate, is reacted with a halo alkanol Grignard reagent.

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Silverman, G., Handbook of Grignard Reagents, 1996, Dekker Publishing, p. 591 (3 pages).
Marshall, J.A., Sn2′ Addtions of Organocopper Reagents to Vinyloxiranes, 1989, Chem. Rev., vol. 89, pp. 1503-1511.
Magid, R.M., Nucleophilic and Organometallic Displacement Reactions of Allylic Compounds: stero- and regiochemistry, 1980, Tetrahedron, vol. 36, pp. 1901-1930.
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