Production of phenols

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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Details

260593A, 260601R, 260606, 260610R, 260632R, 260624R, 260626T, C07C 3700

Patent

active

040061949

ABSTRACT:
Phenols are produced from .alpha.-aralkyl peroxides, preferably alkyl- .alpha. -phenalkyl peroxides or diphenalkyl peroxides, by heating the peroxide in the presence of an acid catalyst and continuously separating volatile reaction products other than the phenol; i.e., a carbonyl compound and alcohol if formed, from the reaction mixture, preferably by bubbling a stripping gas therethrough. Phenol may be produced from an alkyl benzene by reacting the alkyl benzene with t-butyl hydroperoxide to produce a t-butyl- .alpha. -phenalkyl peroxide which is then decomposed in the presence of an acid catalyst. The reaction co-products include t-butanol and a carbonyl compound corresponding to the alkyl group.

REFERENCES:
patent: 2628983 (1953-02-01), Allen et al.
patent: 2883430 (1959-04-01), De Jorg
patent: 2906789 (1959-09-01), McNaughtan
patent: 3365375 (1968-01-01), Nixon

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