Production of particulate polyimide polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528126, 528128, 528172, 528176, 528183, 528229, C08G 6926

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active

049436821

ABSTRACT:
Described is a process for producing, in particulate form, aromatic polyimides based on one or more 2,2-bis[4-(aminophenoxy)-phenyl]hexafluoropropanes. The process involves forming, heating and agitating in a medium composed of dipolar aprotic solvent and liquid aromatic hydrocarbon solvent, a homogeneous solution of a polyamic acid derived from a substantially equimolar mixture of (i) an aromatic tetracarboxylic dianhydride and (ii) a 2,2-bis[4-(aminophenoxy)phenyl]hexafluoropropane, such that a separate phase of particulate aromatic polyimide is formed in such medium. The process avoids difficulties caused by the tendency of the wet polyimide polymer to agglomerate into stringy or tacky masses which can foul reactor and agitator surfaces.

REFERENCES:
patent: 4203922 (1980-05-01), Jones et al.
patent: 4413117 (1983-11-01), Reiter et al.

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