Production of methyl esters and ethylene glycol esters from reac

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2604109R, 518700, 560100, 560103, 560105, 560112, 560123, 560232, 560263, 560265, C09F 508, C07C 6708

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active

045928703

ABSTRACT:
This invention produces methyl esters and ethylene glycol esters by reacting carbon monoxide and hydrogen in a homogeneous liquid phase mixture containing a ruthenium carbonyl complex catalyst and an acyl compound. Methyl ester and ethylene glycol ester are the predominant products. These esters are used as precursors in the formation of ethylene glycol, vinyl acylates such as vinyl acetate, ethylene oxide, ethylene carbonate and methanol.

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Roy L. Pruett, "Industrial Organic Chemicals Through Utilization of Synthesis Gas", Annals of the New York Academy of Sciences, vol. 295, pp. 239-248 (1977).
G. Jenner et al., "Liquid Phase CO--H.sub.2 Reactions in Presence of Ruthenium Catalysts", React. Kinet. Catal. Lett., vol. 15, 103-112 (1980).

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