Production of mannitol and higher manno-saccharide alcohols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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127 36, 127 43, 127 44, 536 41, 536 185, 536124, 568852, 568868, C07C 2914, C07C 3126, C07C 2704, C07G 300

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044840128

ABSTRACT:
A method for hydrolyzing coffee extraction residue materials to produce manno-saccharides having a degree of polymerization from 1 to 10 and subsequently neutralizing and reducing said mixture of manno-saccharides to their corresponding alcohols. The coffee material, preferably spent coffee grounds from a commercial percolation system, is hydrolyzed in a Plug Flow tubular reactor in the presence of an acid catalyst, such as sulfuric acid. Depending on the time, temperature, pressure and catalyst concentration selected, manno-saccharides or mannose is produced. The manno-saccharides or mannose produced are separated from coffee residue material in the form of a syrup and neutralized with calcium hydroxide. The neutralized mixture of manno-saccharides or mannose is reduced to their corresponding alcohols or mannitol.

REFERENCES:
patent: 3579380 (1971-05-01), Friese
patent: 4137395 (1979-01-01), Buckl et al.
patent: 4292451 (1981-09-01), deBerardinis et al.
patent: 4445938 (1984-05-01), Verwaerde et al.

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