Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing
Patent
1981-07-23
1982-11-09
Cooper, Jack
Chemistry of inorganic compounds
Oxygen or compound thereof
Metal containing
106304, 423633, 423634, C01G 4908
Patent
active
043584314
ABSTRACT:
In the production of needle-shaped magnetic iron oxide pigments by treating iron with a nitro-aromatic in the presence of .alpha.-FeOOH nuclei to form .alpha.-FeOOH particles and an amino-aromatic, and thereafter dehydrating the .alpha.-FeOOH particles and reducing them, the improvement which comprises forming the .alpha.-FeOOH nuclei at about 0.degree. to 90.degree. C. in a suspension of metallic iron, an iron-(II)-salt and a nitro-aromatic by adding a basic precipitant in about 10 to 95% of the amount required for the complete precipitation of the iron in the iron-(II)-salt. Advantageously the metallic iron comprises cast iron, the nitro-aromatic comprises nitrobenzene, the amino-aromatic comprises aniline, the basic precipitant comprises at least one of ammonia and a basically reacting alkali metal, alkaline earth metal or ammonium salt, the nuclei formation is carried out at about 10.degree. to 60.degree. C., and the basic precipitant is added in about 20 to 80% of the amount required for the complete precipitation of the iron in the iron-(II)-salt, additional iron and nitrobenzene being added to the suspension of precipitated nuclei to form the .alpha.-FeOOH particles.
REFERENCES:
patent: 3015627 (1962-01-01), Ayers et al.
patent: 4234348 (1980-11-01), Brunn et al.
Bade Heribert
Brunn Horst
Hund Franz
Kiemle Peter
Bayer Aktiengesellschaft
Cooper Jack
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