Production of hydroxymethylbutenoic acids via oxidation

Details Production of hydroxymethylbutenoic acids via oxidation Production of hydroxymethylbutenoic acids via oxidation

1983-04-07

1986-04-08

Berch, Mark L.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D49804, C07B 300

Patent

active

045811733

ABSTRACT:
A useful industrial chemical, oxazolinoazetidinylhydroxymethylbutenoic acid derivative (II) can be produced by oxidizing the corresponding oxazolinoazetidinylhalomethylbutenoic acid derivative(I). ##STR1## wherein R is an alkyl, aralkyl or aryl group, R.sup.1 is a hydrogen atom or a carboxy protecting group and Hal is a halogen atom.

REFERENCES:
Ashurov et al., Chem. Abs. 89, 42303u (1977).
Kyazimov et al., Chem. Abs. 78, 42814j (1972).
MacDonald et al., J. Amer. Chem. Soc. 102, 7760 (1980).
Frimer, J. Org. Chem. 42, p. 3194 (1977).
Hawley, "Condensed Chemical Dictionary" 8th edition p. 787.
Noss et al., Chem. Ber. 89, 2641, 2644 (1956).
Tobolsky et al., "Organic Peroxides" p. 13 (1954).

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