Production of hydroperoxides

Details Production of hydroperoxides Production of hydroperoxides

1975-05-29

1976-10-19

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260586P, 260610B, C07C 2712, C07C 2716

Patent

active

039871150

ABSTRACT:
Method for the production of hydroperoxides of hydrocarbons having no aliphatic or cycloaliphatic tertiary carbon atoms wherein such hydrocarbons are oxidized in the liquid phase with molecular oxygen in the presence of a tertiary alcohol and a tertiary hydroperoxide. This method gives high hydroperoxide selectivities at high conversion levels and at high conversion rates.

REFERENCES:
patent: 2430865 (1947-11-01), Farkes et al.
patent: 2615921 (1952-10-01), Dougherty et al.
patent: 3340304 (1967-09-01), Schulz et al.
patent: 3361807 (1968-01-01), Duncanson et al.
Zaikov et al., Academy of Sciences of the U.S.S.R., No. 3, pp. 598-603 (1968).
Zaikov et al. (II), Izu Akad. Nauk SSSR, fer Khim, 1969(3), pp. 598-603, (Chem. Abst., vol. 71, 122842).

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