Production of hydrogenated hydrocarbons

Mineral oils: processes and products – Phenolic or toxic oils

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201 12, 201 17, 201 21, 201 22, 201 25, 201 28, 201 33, 201 35, 201 38, 208 11R, C10G 100, C10G 106, C10B 4916, C10B 5306

Patent

active

041629590

ABSTRACT:
In a continuous process for recovery of values from a solid carbonaceous material, the carbonaceous material is pyrolyzed in the presence of a particulate source of heat to yield a particulate carbon containing residue of pyrolysis and volatilized hydrocarbons while simultaneously the volatilized hydrocarbons are hydrogenated. The particulate source of heat is formed by oxidizing carbon in the solid residue to heat the particles. Hydrogen for hydrogenation is obtained by reacting at least a portion of the hot particulate carbon containing residue of pyrolysis with steam prior to feeding the hot particulate residue to the pyrolysis reaction zone. Steam and/or carbon dioxide can be introduced into the pyrolysis reaction zone to interact with carbon containing residue contained therein. The particulate source of heat can be introduced to the pyrolysis reaction zone over an overflow weir.

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patent: 3988237 (1976-10-01), Davis et al.

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