Production of hydrogen from oil shale

Chemistry of inorganic compounds – Hydrogen or compound thereof – Elemental hydrogen

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423651, 423652, 423653, 423654, 423415A, 423DIG16, 208 11R, 48197R, C01B 324

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045605475

ABSTRACT:
A process for production of hydrogen from oil shale fines by direct introduction of the oil shale fines into a fluidized bed at temperatures about 1200.degree. to about 2000.degree. F. to obtain rapid heating of the oil shale. The bed is fluidized by upward passage of steam and oxygen, the steam introduced in the weight ratio of about 0.1 to about 10 on the basis of the organic carbon content of the oil shale and the oxygen introduced in less than the stoichiometric quantity for complete combustion of the organic carbonaceous kerogen content of the oil shale. Embodiments are disclosed for heat recovery from the spent shale and heat recovery from the spent shale and product gas wherein the complete process and heat recovery is carried out in a single reaction vessel. The process of this invention provides high conversion of organic carbon component of oil shale and high production of hydrogen from shale fines which when used in combination with a conventional oil shale hydroconversion process results in increased overall process efficiency of greater than 15 percent.

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patent: 4148710 (1979-04-01), Burton
L. Reh, "Fluidized Bed Processing", Chemical Engineering Progress, vol. 67, No. 2, pp. 58-63, Feb. 1971.

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