Production of hydrogen fluoride

Chemistry of inorganic compounds – Halogen or compound thereof – Hydrogen halide

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Details

423339, 423472, 423470, 423490, C01B 722, C01B 3312, C01C 116, C01D 302

Patent

active

040629295

ABSTRACT:
Hydrogen fluoride is produced from hydrofluosilicic acid. The hydrofluosilicic acid is reacted with ammonia. An aqueous solution of ammonium fluoride thus produced is fed with partly recycled alkali metal fluoride to a continuously operated reactor where a bifluoride of the alkali metal is formed in aqueous solution. Reaction mixture is continuously withdrawn and solid alkali metal bifluoride crystallized therefrom. The mother liquor is recycled to the reactor. The solid alkali metal bifluoride is decomposed by heat to produce hydrogen fluoride and solid alkali metal fluoride. The alkali metal fluoride is recycled to the reactor.

REFERENCES:
patent: 3101254 (1963-08-01), Cunningham
patent: 3195979 (1965-07-01), Burkert et al.
patent: 3323861 (1967-06-01), Toyabe et al.

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