Production of hydrocarbyl formates

Details Production of hydrocarbyl formates Production of hydrocarbyl formates

1985-02-15

1991-06-25

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560265, C07C 5112

Patent

active

050269046

ABSTRACT:
Hydrocarbyl formates, convertible by hydrolysis into formic acid, are produced by reacting carbon dioxide and hydrogen with a compound of formula ROH wherein R is a hydrocarbyl group in the presence of a substantially insoluble compound of an element selected from Groups III to VIII of the Periodic Table, which element exhibits amphoteric or basic properties, and as catalyst a compound of a transition metal of Group VIa, VIIa or VIII of the Periodic Table, particularly rhodium, ruthenium or iridium.

REFERENCES:
patent: 3317593 (1967-05-01), Enk et al.
patent: 4299981 (1981-11-01), Leonard

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