Production of hydrocarbons from natural gas

Chemistry: fischer-tropsch processes; or purification or recover – Treatment of feed or recycle stream

Reexamination Certificate

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C518S700000, C518S702000, C518S703000, C518S704000, C518S706000

Reexamination Certificate

active

07879919

ABSTRACT:
A process for producing hydrocarbons from natural gas includes, in a cryogenic separation stage, cryogenically separating the natural gas to produce at least a methane stream and natural gas liquids, in a reforming stage, reforming the methane stream to produce a synthesis gas which includes at least CO and H2, and in a Fischer-Tropsch hydrocarbon synthesis stage, converting at least some of the CO and H2into a Fischer-Tropsch product which includes hydrocarbons. A Fischer-Tropsch tail gas which includes at least CO and H2, methane and heavier than methane hydrocarbons, is separated from the Fischer-Tropsch product in a Fischer-Tropsch product separation stage. At least a portion of the Fischer-Tropsch tail gas is recycled to the cryogenic separation stage, where the Fischer-Tropsch tail gas is cryogenically separated into two or more streams.

REFERENCES:
patent: 5763716 (1998-06-01), Benham et al.
patent: 6214258 (2001-04-01), Woodward et al.
patent: 2004/0177646 (2004-09-01), Wilkinson et al.
patent: 2005/0113463 (2005-05-01), O'Rear et al.
patent: 0979 983 (2000-02-01), None
patent: 2 168 719 (1986-06-01), None
patent: WO 98/50326 (1998-11-01), None
patent: WO 01/10979 (2001-02-01), None
patent: WO 2004/015028 (2004-02-01), None
PCT Search Report and Written Opinion for PCT/IB2006/054768 dated Sep. 3, 2007.

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