Metal founding – Process – Shaping liquid metal against a forming surface
Reexamination Certificate
1999-11-30
2002-05-07
Elve, M. Alexandra (Department: 1725)
Metal founding
Process
Shaping liquid metal against a forming surface
C164S015000
Reexamination Certificate
active
06382299
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention:
This invention pertains to hollow metal microcylinders produced from diacetylenic lipids by self-assembly and to a process for making same.
2. Description of Related Art
Organic tubules formed from a diacetylenic lipid by self-assembly were first publicly described in 1984 and achieved by a process of lipsomomal cooling. The lipid, i.e., 1,2-bis(10,12-tricosadiynoyl1)-sn-glycero-3-phosphocholine (DC-8,9-PC), was heated in water above 50° C. and cooled. Upon cooling below the melting temperature of 42° C., the liposomes were observed to convert to tubules of sub-micron diameter by self-assembly. Later it was demonstrated how the tubules could be generated from the same lipid by the addition of water as a non-solvent to a solution of the lipid in alcohol or propylene glycol. The tubules were allowed to grow for periods up to 6 months and resulted in average lengths of up to 100 microns. Still later, the role of alcohols in tubule formation was further investigated. The lipid, i.e., DC-8,9-PC, in alcohol/water solutions, was heated to 60° C. and tubules were formed by cooling to room temperature. The solvent 85% methanol was found to yield tubules with the greatest lengths with an average of 65 microns.
Preparation of metallized derivatives from lipid tubules was reported in 1987. Permalloy-coated tubules have been used in composites to produce high-dielectric, low-loss materials by aligning the tubules with a magnetic field and similar technique was used to produce composites with significant ferromagnetic properties. The prior art tubules were not electrically conducting probably due to the fact that electroless metal plating was conducted to the point when bubbling commenced indicating that the bath was not exhausted and an insufficient amount of metal was plated on the tubules. A successful application of this technology was demonstrated in 1992 by aligning metallized tubules in a magnetic field and cast in epoxy. Subsequently, the epoxy was etched away and the surface sputter-coated with gold. This structure was used to show a very low vacuum field emission of less than 10 &mgr;A.
Progress in the application of tubule technology has been held back by the non-uniformity and incompleteness of the metal coating. Further, the coating consisted in a large part of metals and metallic oxides, such as nickel and nickel oxides, rather than a metallic alloy, such as nickel alloy.
OBJECTS AND BRIEF SUMMARY OF THE INVENTION
An object of this invention is a process for making hollow metal microcylinders from diacetylenic lipids by self-assembly characterized by using as received technical grade diacetylenic lipids without preliminary purification, resulting in a more efficient use of lipids.
Another object of this invention is hollow metal microcylinders in free-flowing powder form.
Another aspect of the invention is the electrically conductive metal microcylinders.
Another object of this invention is electrically conducting metal microcylinders made from a diacetylenic lipid by self-assembly which are devoid of the lipid.
These and other objects of this invention can be achieved by making the microcylinders from diacetylenic lipids by self assembly thereof to produce lipid tubules, and then metallizing these tubules by plating at least one metal thereon to make the metallized tubules and then metal microcylinders which are electrically conducting and/or magnetically sensitive.
REFERENCES:
patent: 4911981 (1990-03-01), Schnur et al.
patent: 5492696 (1996-02-01), Price et al.
patent: 6013206 (2000-01-01), Price et al.
Elve M. Alexandra
Kap George A..
Karasek John J.
McHenry Kevin
The United States of America as represented by the Secretary of
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